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Molecular Engineering of trifunctional supported catalysts for the aerobic oxidation of alcohols

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Fernandes, Antony E. [Massachusetts Institute of Technology (USA)] Riant, Olivier [UCL] Jensen, Klavs F. [Massachusetts Institute of Technology (USA)] Jonas, Alain M. [UCL]

We describe a simple and general method for the preparation and molecular engineering of supported trifunctional catalysts and their application in the representative Cu/TEMPO/NMI-catalyzed aerobic oxidation of benzyl alcohol. The methodology allows in one single step to immobilize, with precise control of surface composition, both pyta, CuI, TEMPO, and NMI sites on azide-functionalized silica particles. To optimize the performance of the heterogeneous trifunctional catalysts, synergistic interactions are finely engineered through modulating the degree of freedom of the imidazole site as well as tuning the relative surface composition,leading to catalysts with an activity significantly superior to the corresponding homogeneous catalytic system.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2016
Language Anglais
Journal information "Angewandte Chemie (International Edition)" - Vol. 55, p. 11044-11048 (2016)
Peer reviewed yes
Publisher Wiley - V C H Verlag GmbH & Co. KGaA ((Germany) Weinheim)
issn 1433-7851
e-issn 1521-3773
Publication status Publié
Affiliation UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
Links
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Bibliographic reference Fernandes, Antony E. ; Riant, Olivier ; Jensen, Klavs F. ; Jonas, Alain M.. Molecular Engineering of trifunctional supported catalysts for the aerobic oxidation of alcohols. In: Angewandte Chemie (International Edition), Vol. 55, p. 11044-11048 (2016)
Permanent URL http://hdl.handle.net/2078.1/181260