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One “Click” to controlled bifunctional supported catalysts for the Cu/TEMPO-catalyzed aerobic oxidation of alcohols

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Fernandes, Antony E. [UCL] Riant, Olivier [UCL] Jonas, Alain M. [UCL] Jensen, Klavs F. [Massachusett Instutute of Technology, USA]

A simple and reliable methodology is described for the preparation of heterogeneous bifunctional catalysts with a high control over surface composition. The strategy relies on the grafting of a mix of catalytic components from an azide-functionalized silica platform using the CuAAC reaction. The resulting finely engineered supported catalysts are employed in the model Cu/TEMPO-catalyzed aerobic oxidation of benzylic alcohol.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2016
Language Anglais
Journal information "RSC Advances" - Vol. 6, p. 36602-36605 (07/04/2016)
Peer reviewed yes
Publisher Royal Society of Chemistry (London UK)
issn 2046-2069
e-issn 2046-2069
Publication status Publié
Affiliations UCL - SST/IMCN/BSMA - Bio and soft matter
UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
Links
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Bibliographic reference Fernandes, Antony E. ; Riant, Olivier ; Jonas, Alain M. ; Jensen, Klavs F.. One “Click” to controlled bifunctional supported catalysts for the Cu/TEMPO-catalyzed aerobic oxidation of alcohols. In: RSC Advances, Vol. 6, p. 36602-36605 (07/04/2016)
Permanent URL http://hdl.handle.net/2078.1/173387