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Carbon Redox-Polymer-Gel Hybrid Supercapacitors

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Vlad, Alexandru [UCL] Singh, N. [Rice University Houston, USA] Melinte, Sorin [UCL] Gohy, Jean-François [UCL] Ajayan, P.M. [Rice University Houston, USA]

Energy storage devices that provide high specific power without compromising on specific energy are highly desirable for many electric-powered applications. Here, we demonstrate that polymer organic radical gel materials support fast bulk-redox charge storage, commensurate to surface double layer ion exchange at carbon electrodes. When integrated with a carbon-based electrical double layer capacitor, nearly ideal electrode properties such as high electrical and ionic conductivity, fast bulk redox and surface charge storage as well as excellent cycling stability are attained. Such hybrid carbon redox-polymer-gel electrodes support unprecedented discharge rate of 1,000C with 50% of the nominal capacity delivered in less than 2 seconds. Devices made with such electrodes hold the potential for battery-scale energy storage while attaining supercapacitor-like power performances.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès libre
Publication date 2016
Language Anglais
Journal information "Scientific Reports" - Vol. 6, p. 22194
Peer reviewed yes
Publisher Nature Publishing Group ((United Kingdom) London)
issn 2045-2322
e-issn 2045-2322
Publication status Publié
Affiliation UCL - SST/ICTM/ELEN - Pôle en ingénierie électrique
Keywords Supercapacitors ; Energy storage
Links
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Bibliographic reference Vlad, Alexandru ; Singh, N. ; Melinte, Sorin ; Gohy, Jean-François ; Ajayan, P.M.. Carbon Redox-Polymer-Gel Hybrid Supercapacitors. In: Scientific Reports, Vol. 6, p. 22194
Permanent URL http://hdl.handle.net/2078.1/172163