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Synthesis of polymer precursors of electroactive materials by SET-LRP

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Bertrand, Olivier [UCL] Ernould, Bruno [UCL] Boujioui, Fadoi [UCL] Vlad, Alexandru [UCL] Gohy, Jean-François [UCL]

The synthesis of electroactive polymer precursors by single electron transfer-living radical polymerisation (SET-LRP) is demonstrated here. Standard SET-LRP conditions are employed for the controlled polymerisation of 2,2,6,6-tetramethylpiperidin-4-yl methacrylate (TMPM). The controlled behaviour of the polymerisation under these conditions is demonstrated by kinetic experiments. Moreover, the synthesis of functional block copolymers is investigated with 3-azidopropyl methacrylate (AzPMA). The TMPM containing (co)polymers are oxidised to produce electroactive poly(TEMPO methacrylate) (PTMA). The redox behaviour of the PTMA was furthermore evidenced by cyclic voltamperometry. These polymers are promising in the frame of organic radical batteries.

Document type Article de périodique (Journal article) – Article de recherche
Publication date 2015
Language Anglais
Journal information "Polymer Chemistry" - Vol. 6, no.33, p. 6067-6072 (2015)
Peer reviewed yes
Publisher Royal Society of Chemistry
issn 1759-9954
e-issn 1759-9962
Publication status Publié
Affiliations UCL - SST/IMCN/BSMA - Bio and soft matter
UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
Links
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Bibliographic reference Bertrand, Olivier ; Ernould, Bruno ; Boujioui, Fadoi ; Vlad, Alexandru ; Gohy, Jean-François. Synthesis of polymer precursors of electroactive materials by SET-LRP. In: Polymer Chemistry, Vol. 6, no.33, p. 6067-6072 (2015)
Permanent URL http://hdl.handle.net/2078.1/170354