Johnson, B.F.G.
[autre]
Hermans, Sophie
[UCL]
Khimyak, T.
[autre]
The reaction of the dianion [Ru5C(CO)14]12- with [PtCl2- (MeCN)2] in the presence of silica yields [Ru5PtC(CO)16] (1) and the new compound [PPN]2[Ru10Pt2C2(CO) 28] (2), while, in a related reaction, [Ru6C(CO)16]2- undergoes addition of [PtCl2(MeCN)2] to yield the cluster [Ru12PtC2(CO)32- (MeCN)2] (3). The high nuclearity compounds 2 and 3 have been fully characterized and their structures determined by single crystal X-ray analysis. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
| Bibliographic reference |
Johnson, B.F.G. ; Hermans, Sophie ; Khimyak, T.. Synthesis and structure of two new high nuclearity Ru/Pt mixed-metal clusters. In: European Journal of Inorganic Chemistry, no. 7, p. 1325-1331 (2003) |
| Permanent URL |
http://hdl.handle.net/2078.1/127346 |
