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Screening of metal borohydrides by mechanochemistry and diffraction

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Ravnsbœk, D.B. [Aarhus University (Denmark)] Sørensen, L.H. [Aarhus University (Denmark)] Filinchuk, Yaroslav [UCL] Besenbacher, F. [University of Geneva (Switzerland)] Jensen, T.R. [University of Geneva (Switzerland)]

Ay, there's the rub: The formation of cadmium-based borohydrides is screened by mechanochemical synthesis using various reactants in different ratios. Sequential in situ variable-temperature diffraction studies provide simultaneous information about composition, structure, decomposition pathways, and properties of the compounds. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2012
Language Anglais
Journal information "Angewandte Chemie (International Edition)" - Vol. 51, no. 15, p. 3582-3586 (2012)
Peer reviewed yes
Publisher Wiley - V C H Verlag GmbH & Co. KGaA ((Germany) Weinheim)
issn 1433-7851
e-issn 1521-3773
Publication status Publié
Affiliation UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
Keywords Ball milling ; Mechano-chemistry ; Mechanochemical synthesis ; Screening methods ; Structure elucidation ; Variable temperature ; Ball milling ; Cadmium ; Diffraction ; Diagnosis ; Borohydrides ; Cadmium ; Screening methods ; Structure elucidation ; Borohydrides ; Decomposition pathway ; Diffraction studies ; In-situ
Links
  1. Jensen Torben R., Nielsen Thomas K., Filinchuk Yaroslav, Jørgensen Jens-Erik, Cerenius Yngve, Gray Evan MacA., Webb Colin J., Versatilein situpowder X-ray diffraction cells for solid–gas investigations, 10.1107/s0021889810038148
  2. Ravnsbæk Dorthe B., Filinchuk Yaroslav, Cerný Radovan, Jensen Torben R., Powder diffraction methods for studies of borohydride-based energy storage materials, 10.1524/zkri.2010.1357
  3. Černý Radovan, Filinchuk Yaroslav, Complex inorganic structures from powder diffraction:case of tetrahydroborates of light metals, 10.1524/zkri.2011.1409
  4. Filinchuk Yaroslav, Chernyshov Dmitry, Dmitriev Vladimir, Light metal borohydrides: crystal structures and beyond, 10.1524/zkri.2008.1021
  5. Filinchuk Yaroslav, Richter Bo, Jensen Torben R., Dmitriev Vladimir, Chernyshov Dmitry, Hagemann Hans, Porous and Dense Magnesium Borohydride Frameworks: Synthesis, Stability, and Reversible Absorption of Guest Species, 10.1002/ange.201100675
  6. Filinchuk Yaroslav, Richter Bo, Jensen Torben R., Dmitriev Vladimir, Chernyshov Dmitry, Hagemann Hans, Porous and Dense Magnesium Borohydride Frameworks: Synthesis, Stability, and Reversible Absorption of Guest Species, 10.1002/anie.201100675
  7. Orimo Shin-ichi, Nakamori Yuko, Eliseo Jennifer R., Züttel Andreas, Jensen Craig M., Complex Hydrides for Hydrogen Storage, 10.1021/cr0501846
  8. Rude Line H., Nielsen Thomas K., Ravnsbaek Dorthe B., Bösenberg Ulrike, Ley Morten B., Richter Bo, Arnbjerg Lene M., Dornheim Martin, Filinchuk Yaroslav, Besenbacher Flemming, Jensen Torben R., Tailoring properties of borohydrides for hydrogen storage: A review, 10.1002/pssa.201001214
  9. Sundqvist, Diffus. Defect Data Pt. B, 150, 175 (2009)
  10. Nakamori Yuko, Miwa Kazutoshi, Ninomiya Akihito, Li Haiwen, Ohba Nobuko, Towata Shin-ichi, Züttel Andreas, Orimo Shin-ichi, Correlation between thermodynamical stabilities of metal borohydrides and cation electronegativites: First-principles calculations and experiments, 10.1103/physrevb.74.045126
  11. Hagemann Hans, Longhini Moïse, Kaminski Jakub W., Wesolowski Tomasz A., Černý Radovan, Penin Nicolas, Sørby Magnus H., Hauback Bjørn C., Severa Godwin, Jensen Craig M., LiSc(BH4)4: A Novel Salt of Li+and Discrete Sc(BH4)4−Complex Anions, 10.1021/jp803201q
  12. Purewal Justin, Hwang Son-Jong, Bowman, Jr. Robert C., Rönnebro Ewa, Fultz Brent, Ahn Channing, Hydrogen Sorption Behavior of the ScH2−LiBH4System: Experimental Assesment of Chemical Destabilization Effects, 10.1021/jp800486n
  13. Černý Radovan, Severa Godwin, Ravnsbæk Dorthe B., Filinchuk Yaroslav, D’Anna Vincenza, Hagemann Hans, Haase Dörthe, Jensen Craig M., Jensen Torben R., NaSc(BH4)4: A Novel Scandium-Based Borohydride, 10.1021/jp908397w
  14. Černý Radovan, Ravnsbæk Dorthe B., Severa Godwin, Filinchuk Yaroslav, D’ Anna Vincenza, Hagemann Hans, Haase Dörthe, Skibsted Jørgen, Jensen Craig M., Jensen Torben R., Structure and Characterization of KSc(BH4)4, 10.1021/jp106280v
  15. Ravnsbaek Dorthe, Filinchuk Yaroslav, Cerenius Yngve, Jakobsen Hans J., Besenbacher Flemming, Skibsted Jørgen, Jensen Torben R., A Series of Mixed-Metal Borohydrides, 10.1002/ange.200903030
  16. Ravnsbaek Dorthe, Filinchuk Yaroslav, Cerenius Yngve, Jakobsen Hans J., Besenbacher Flemming, Skibsted Jørgen, Jensen Torben R., A Series of Mixed-Metal Borohydrides, 10.1002/anie.200903030
  17. Ravnsbæk D.B., Frommen C., Reed D., Filinchuk Y., Sørby M., Hauback B.C., Jakobsen H.J., Book D., Besenbacher F., Skibsted J., Jensen T.R., Structural studies of lithium zinc borohydride by neutron powder diffraction, Raman and NMR spectroscopy, 10.1016/j.jallcom.2010.11.008
  18. Ravnsbaek Dorthe B., Sørensen Lise H., Filinchuk Yaroslav, Reed Daniel, Book David, Jakobsen Hans J., Besenbacher Flemming, Skibsted Jørgen, Jensen Torben R., Mixed-Anion and Mixed-Cation Borohydride KZn(BH4)Cl2: Synthesis, Structure and Thermal Decomposition, 10.1002/ejic.201000119
  19. Li H.-W., Orimo S., Nakamori Y., Miwa K., Ohba N., Towata S., Züttel A., Materials designing of metal borohydrides: Viewpoints from thermodynamical stabilities, 10.1016/j.jallcom.2007.02.156
  20. Schrauzer Gerhard Norbert, �ber ein Periodensystem der Metallboranate, 10.1007/bf00599819
  21. Černý Radovan, Penin Nicolas, D’Anna Vincenza, Hagemann Hans, Durand Etienne, Růžička Jakub, MgxMn(1−x)(BH4)2 (x=0–0.8), a cation solid solution in a bimetallic borohydride, 10.1016/j.actamat.2011.04.052
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  25. Favre-Nicolin Vincent, Černý Radovan, FOX, `free objects for crystallography': a modular approach toab initiostructure determination from powder diffraction, 10.1107/s0021889802015236
  26. Černý Radovan, Filinchuk Yaroslav, Hagemann Hans, Yvon Klaus, Magnesium Borohydride: Synthesis and Crystal Structure, 10.1002/anie.200700773
  27. Černý Radovan, Filinchuk Yaroslav, Hagemann Hans, Yvon Klaus, Magnesium Borohydride: Synthesis and Crystal Structure, 10.1002/ange.200700773
  28. Filinchuk Yaroslav, Černý Radovan, Hagemann Hans, Insight into Mg(BH4)2with Synchrotron X-ray Diffraction: Structure Revision, Crystal Chemistry, and Anomalous Thermal Expansion, 10.1021/cm803019e
  29. Ravnsbæk Dorthe B., Filinchuk Yaroslav, Černý Radovan, Ley Morten B., Haase Dörthe, Jakobsen Hans J., Skibsted Jo̷rgen, Jensen Torben R., Thermal Polymorphism and Decomposition of Y(BH4)3, 10.1021/ic902279k
  30. Jaroń Tomasz, Grochala Wojciech, Y(BH4)3—an old–new ternary hydrogen store akalearning from a multitude of failures, 10.1039/b910698g
  31. Borgschulte A., Callini E., Probst B., Jain A., Kato S., Friedrichs O., Remhof A., Bielmann M., Ramirez-Cuesta A. J., Züttel A., Impurity Gas Analysis of the Decomposition of Complex Hydrides, 10.1021/jp205566q
Bibliographic reference Ravnsbœk, D.B. ; Sørensen, L.H. ; Filinchuk, Yaroslav ; Besenbacher, F. ; Jensen, T.R.. Screening of metal borohydrides by mechanochemistry and diffraction. In: Angewandte Chemie (International Edition), Vol. 51, no. 15, p. 3582-3586 (2012)
Permanent URL http://hdl.handle.net/2078.1/126359