Bauer, W.
[Universitat Bayreuth (Germany)]
DÎrtu, Marinela Maria
[UCL]
Garcia, Yann
[UCL]
Weber, B.
[Universitat Bayreuth (Germany)]
The synthesis and characterisation of seven iron(ii) 1D chain coordination polymers with tetradentate Schiff-base like equatorial ligands and bis(4-pyridylmethyl)sulfide (bpms) as a flexible bridging axial ligand is reported. This new family of materials displays a wide spectrum of spin transition properties in the solid state ranging from gradual, abrupt, incomplete to even step-wise that have all been characterized by SQUID magnetometry. The X-ray structure analysis of two complexes at several temperatures is discussed in the frame of their spin crossover properties. © 2012 The Royal Society of Chemistry.
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Bibliographic reference |
Bauer, W. ; DÎrtu, Marinela Maria ; Garcia, Yann ; Weber, B.. Iron(II) spin transition coordination polymers with a zigzag structure . In: CrystEngComm, Vol. 14, no.4, p. 1223-1231 (2012) |
Permanent URL |
http://hdl.handle.net/2078.1/125487 |