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Functionalized Phosphonated Half-Cage Molecules as Ligands for Metal Complexes

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Villemin, Elise [UCL] Herent, Marie-France [UCL] Marchand-Brynaert, Jacqueline [UCL]

Phosphonated molecules, featuring a half-cage structure and a N-lateral chain with additional metal coordinating groups were designed as ligands of metal cations. These compounds were synthesized by a Diels-Alder (DA) strategy, using 1-diethoxyphosphoryl-1,3-butadiene and a series of N-substituted maleimides as dienophiles. Two cycloadducts, bearing a terminal primary alcohol and a terminal iodide, respectively, were used as key intermediates for further functionalizations. Metal coordination properties of the ligands equipped with functionalized N-lateral chains were proven by an ESI-HRMS study. The stoichiometry of one selected Eu III complex with a diphosphonated ligand was determined by photoluminescence spectroscopy in emission mode

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2012
Language Anglais
Journal information "European Journal of Organic Chemistry" - Vol. 2012, no.31, p. 6165-6178 (2012)
Peer reviewed yes
Publisher Wiley - V C H Verlag GmbH & Co. KGaA ((Germany) Weinheim)
issn 1434-193X
e-issn 1099-0690
Publication status Publié
Affiliations UCL - SSS/LDRI - Louvain Drug Research Institute
UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
Keywords Chelates ; Cycloaddition ; Luminescence ; P ligands
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Bibliographic reference Villemin, Elise ; Herent, Marie-France ; Marchand-Brynaert, Jacqueline. Functionalized Phosphonated Half-Cage Molecules as Ligands for Metal Complexes. In: European Journal of Organic Chemistry, Vol. 2012, no.31, p. 6165-6178 (2012)
Permanent URL http://hdl.handle.net/2078.1/120810